Molecular Engineering of Push–Pull Porphyrin Dyes for Highly Efficient Dye‐Sensitized Solar Cells: The Role of Benzene Spacers

Porphyrins have drawn much attention as sensitizers owing to the large absorption coefficients of their Soret and Q bands in the visible region. In a donor and acceptor zinc porphyrin we applied a new strategy of introducing 2,1,3‐benzothiadiazole (BTD) as a π‐conjugated linker between the anchoring group and the porphyrin chromophore to broaden the absorption spectra to fill the valley between the Soret and Q bands. With this novel approach, we observed 12.75 % power‐conversion efficiency under simulated one‐sun illumination (AM1.5G, 100 mW cm^?2). In this study, we showed the importance of introducing the phenyl group as a spacer between the BTD and the zinc porphyrin in achieving high power‐conversion efficiencies. Time‐resolved fluorescence, transient‐photocurrent‐decay, and transient‐photovoltage‐decay measurements were employed to determine the electron‐injection dynamics and the lifetime of the photogenerated charge carriers.     

Redox Chemistry of a Hydroxyphenyl‐Substituted Borane

Chemical reduction of a hydroxyphenyl‐substituted borane triggers a sequential electron‐ and intramolecular hydrogen‐atom‐transfer process to afford a hydridoborate phenoxide dianion. On the other hand, hydrogen‐atom abstraction of the borane leads to the isolation of a neutral borylated phenoxyl radical, which can be transformed to the corresponding benzoquinone borataalkene derivative by reduction with cobaltocene.     

Development and validation of an ELISA kit for the detection of ricin toxins from biological specimens and environmental samples

Ricin is a toxin that can be easily extracted from seeds of Ricinus communis plants. Ricin is considered to be a major bio-threat as it can be freely and easily acquired in large quantities. A deliberate release of such toxin in civilian populations would very likely overwhelm existing public health systems, resulting in public fear and social unrest. There is currently no commercially available or FDA-approved prophylaxis such as vaccines, or therapeutic antitoxins or antidotes, available for ricin intoxication. Patient treatment is typically supportive care based on symptoms, often designed to reinforce the body’s natural response. This paper describes the development and validation of a robust ELISA test kit, which can be used to screen for ricin in biological specimens such as whole blood and faeces. Faecal specimens are shown in this study to have better diagnostic sensitivity and a wider diagnostic window compared to whole blood. From these results, it is concluded that faeces is the most suitable clinical specimen for diagnosis of ricin poisoning via the oral route. The ELISA test kit can also detect ricin in environmental samples. An advantage of this ELISA kit over other commercial off-the-shelf (COTS) detection kits currently on the market that are developed to screen environmental samples only is its ability to diagnose ricin poisoning from clinical specimens as well as detect ricin from environmental samples.     

Fuel spray visualization and its impingement analysis on in-cylinder surfaces in a direct-injection spark-ignition engine

Abstract  

Experiments are performed to investigate the effects of fuel spray on in-cylinder mixture preparation and its impingement on cylinder walls and piston top inside a direct-injection spark-ignition engine with optical access to the cylinder. Novel image processing algorithms are developed to analyze the fuel impingement quantitatively on in-cylinder surfaces. The technique is useful to optimize the fuel pressure, injection timing and the number of injections to minimize the fuel impingement on in-cylinder surfaces. E85, which represents a blend of 85% ethanol and 15% gasoline (by volume) is used in this study. Two types of fuel injectors are used; (i) low-pressure production-intent injector with fuel pressure of 3 MPa, and (ii) high-pressure production injector with fuel pressures of 5 and 10 MPa. In addition, the effects of split injection are also presented by maintaining the same amount of fuel used in single injection. It is found that the split injection is an effective way to reduce the overall fuel impingement on in-cylinder surfaces while maintaining a reasonably good air–fuel mixture in the cylinder.     

Improvement of <Emphasis Type="Italic">n</Emphasis>-ZnO/<Emphasis Type="Italic">p</Emphasis>-Si photodiodes by embedding of silver nanoparticles

The photo-current of n-ZnO/p-Si heterojunction photodiodes was improved by embedding Ag nanoparticles in the interface (ZnO/nano-P_Ag/p-Si), and the ratio between photo- and dark-current increased by about three orders more than that of a n-ZnO/p-Si specimen. The improvement in the photo-current resulted from the light scattering of embedded Ag nanoparticles. The I–V curve of n-ZnO/p-Si degraded after thermal treatment (A-ZnO/p-Si) because the silicon robbed the oxygen from ZnO to form amorphous silicon dioxide and left an oxygen vacancy. Notably, the properties of ZnO/nano-P_Ag/p-Si were better in the time-dependent photoresponse under 10 V bias. Ag nanoparticles (15–20 nm) scattered the UV light randomly and increased the probability for the absorption of ZnO to enhance the properties of the photodiode.     

Determination of microelement distribution in different components of soil-plant systems

The leaves, stem, and roots of two types of shrubs (tea (Camellia sinensis) and sweet leaf (Sauropus androgynus)) and two types of herbs (vetiver grass (Vetiveria zizanioides L. Nash) and maize (Zea mays L)) and the Thucuc soil where the plants were growing were collected to be studied. The contents of 22 elements in the samples were determined by three methods: X-Ray fluorescence analysis (XRFA), gamma activation analysis (GAA), and the tracking method to study the distribution of these elements in plants and the soil-plant relationship. This study was carried out at the Flerov Laboratory of Nuclear Reactions (FLNR), Joint Institute for Nuclear Research (JINR), Dubna, Russia. The distribution of the elements in the soil-plant system was studied.     

An inventory model with generalized type demand,deterioration and backorder rates

This study is motivated by the paper of Skouri et al. [Skouri, Konstantaras, Papachristos, Ganas, European Journal of Operational Research 192 (1) (2009) 79–92]. We extend their inventory model from ramp type demand rate and Weibull deterioration rate to arbitrary demand rate and arbitrary deterioration rate in the consideration of partial backorder. We demonstrate that the optimal solution is actually independent of demand. That is, for a finite time horizon, any attempt at tackling targeted inventory models under ramp type or any other types of the demand becomes redundant. Our analytical approach dramatically simplifies the solution procedure.     

A heterogeneous cooperative parallel search of branch-and-bound method and tabu search algorithm

In this study, we present a heterogeneous cooperative parallel search that integrates branch-and-bound method and tabu search algorithm. These two algorithms perform searches in parallel and cooperate by asynchronously exchanging information about the best solutions found and new initial solutions for tabu search. The rapid production of a good solution from the tabu search process provides the branch-and-bound process with a better feasible solution to accelerate the elimination of subproblems that do not contain an optimal solution. The new initial solution produced from the subproblem with a least-cost lower bound of the branch-and-bound method suggests the best potential area for tabu search to explore. We use a master-slave model to reduce the complexity of communication and enhance the performance of data exchange. A branch-and-bound process is used as the master process to control the exchange of information and the termination of computation. Several tabu search processes are executed simultaneously as the slave processes and cooperate by asynchronously exchanging information on the best solutions found and the new initial solutions by the master process of branch-and-bound. Based on the computation experiments of solving traveling salesman problems (TSP), the proposed heterogeneous parallel search algorithm outperforms a conventional parallel branch-and-bound method and a conventional parallel tabu search. We also present the computational results showing the efficiency of heterogeneous cooperative parallel search when we use more processors to accelerate search time. Thus, the proposed heterogeneous parallel search algorithm achieves linear accelerations.     

Hybrid control for synchronizing a chaotic system

In this paper, a hybrid control based on pulse width modulator (PWM) is proposed to synchronize a class of master–slave chaotic systems with uncertainties. We use the Genetic Algorithm (GA) together with fuzzy logic to tune the switching time of PWM mode controller such that the output response of master–slave chaotic system can be synchronized. Finally, an example, uncertain master–slave Duffing–Holmes chaos system, is proposed to show the proposed method’s effectiveness for chaotic synchronization.     

Analytical study of an active piezoelectric absorber on vibration attenuation of a plate

The attenuation of the transverse vibration of a plate, subjected to a harmonic force, is studied. This goal can be achieved by using an active dynamic absorber. The active absorber is made of a pair of piezoelectric sheets, attached to both sides of the plate, and closed electric circuits. One piece of the piezoelectric material provides a sensor for detecting the motion of the plate. Another piece serves as an active dynamic absorber. The equations of motion of the composite plate, including the plate and the piezoelectric material, and the circuit equations of the sensor and the absorber are derived. The displacements of the plate and the currents in the circuits are calculated. The active absorber can successfully attenuate the vibration. The numerical results show that the proposed active absorber can offer more reduction than that using a passive absorber while the absorber is designed to suppress the resonance of a particular vibration mode. Moreover, the active absorber can also reduce the displacements corresponding to other uncontrolled modes. The effects of altering various parameters of the active absorber are studied and discussed.